Eddy-Contact Micromixing
Liquid-liquid reactions can be modeled using Eddy Contact Micromixing in which the reaction rate is determined by an expression that accounts for the molecular micromixing process. Liquids generally have small molecular diffusivity, and reaction is limited by the rate that reactants can diffuse to the liquid-liquid interface. The ECM model models this effect by increasing the time-scale for reaction.
Reaction System
The Eddy-Contact Micromixing model uses a reaction system similar to that of the Eddy Break-Up model. See Eddy Break-Up: Reaction System.
Source Term Definition
The source terms for Eddy-Contact Micromixing are calculated from Eqn. (3412) using reaction rates that are calculated differently depending on which of the following methods are used.
For a reaction of the form Eqn. (3353):
- With standard eddy contact micromixing (convection
limited), the rate of fuel depletion is assumed to be Eqn. (3454).
In which the source term, is Eqn. (3456).
The mixing time scale in Eqn. (3454) is calculated by one of two options:- Kolmogorov Method
(3487)
Where is the turbulent dissipation rate, is the kinematic viscosity, and is a constant (mixing coefficient) with a default value of 0.04.
- Classical Scalar
Dissipation
(3488)Where is the turbulent kinetic energy, is a constant (mixing coefficient) with a default value of 1.0, and is the Schmidt number. Unlike gases, for liquids the molecular mixing is slow, which means that .
The final reaction rate of species is the minimum of the mixing rate that is calculated by Eqn. (3487) or Eqn. (3488) and the kinetic rate that is calculated by Eqn. (3362).
- Kolmogorov Method
- With no micromixing (Kinetics Only), the rate of fuel depletion is assumed to be dictated by finite-rate chemical kinetics. Therefore, the source term is calculated by Eqn. (3412) using the reaction rate that is calculated by Eqn. (3362).
Solution Procedure
The Eddy-Contact Micromixing model solves liquid-liquid reactions in the same way as Eddy Break-Up reactions are solved. See Eddy Break-Up: Solution Procedure.